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A green synthesis of nitrones from diamino glyoxime …

Nickel-induced DNA damage/alterations that have been reported include: conformational transitions of the DNA from the normal right-handed B-helix to the left-handed Z helix (van de Sande et al., 1982; Boutayre et al., 1984), infidelity of DNA synthesis, as shown with cell-free systems using synthetic templates (Sirover & Loeb, 1977; Zakour et al, 1981), and inhibition of DNA synthesis in a wide variety of organisms extending to inhibition of DNA excision repair (Table 27).

Occupations with potential exposure to nickela-------------------------------------------------------------Battery makers, storage Nickel-alloy makersCashiers Nickel minersCatalyst workers Nickel refinersCemented-carbide makers Nickel smeltersCeramic makers Oil hydrogenatorsDisinfectant makers Organic-chemical synthesizersDyers Paint makersElectroplaters Penpoint makersEnamellers Petroleum-refinery workersGas-mask makers Spark-plug makersGlass makersb Stainless-steel makersInk makers Textile dyersJewellers Vacuum-tube makersMagnet makers Varnish makersMetallizers WeldersMond-process workers-------------------------------------------------------------a Adapted from: US NIOSH (1977b).

Nickel compounds inhibited DNA synthesis in a wide variety of organisms.
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K. Barry Sharpless -- Publications

Sharpless, Arenesulfonate Derivatives of Homochiral Glycidol: Versatile Chiral Building Blocks for Organic Synthesis,
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Sharpless, Syntheses of Diols by Catalytic Dihydroxylation Reactions, "Applied Homogeneous Catalysis by Organometallic Complexes", Boy Cornils and Wolfgang A.

Living free-radical polymerization - Wikipedia

Sharpless, Asymmetric Aminohydroxylation, in
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Nickel (EHC 108, 1991) - INCHEM


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