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Involved in the biosynthesis of tri- and tetraketide alpha-pyrones

A novel mannosylated human serum albumin (MSA) was synthesized by coupling α-D-mannopyranosylphenylisothiocyanate to HSA and then to NOTA active ester (NOTA-MSA) [].

Triazacyclononane with either hydroxybenzyl or hydroxypyridyl pendant arms at the nitrogens (TACN-meHP (16), TACN-TX (17), TACN-HP (18), TACN-HB (19), TACN-TM-Bn (20) Figure ) were synthesized in order to increase the lipophilicity of gallium complexes and enable the blood brain barrier penetration [].

Novel 2-Pyrone Synthesis via Michael Addition of …
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Recent Advances in the Synthesis of 2-Pyrones - MDPI

We synthesized a series of tricyclic pyrone derivatives and evaluated their counteraction on amyloid toxicity.
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(Figure Presented) The winner takes it aldol: The total synthesis of auripyrones A and B was achieved using a diastereoselective aldol-type reaction with 2, 6-diethyl-3, 5-dimethyl-4-pyrone as a key step. The stereostructure and absolute configura-tion of auripyrone B has also been determined.

N2 - (Figure Presented) The winner takes it aldol: The total synthesis of auripyrones A and B was achieved using a diastereoselective aldol-type reaction with 2, 6-diethyl-3, 5-dimethyl-4-pyrone as a key step. The stereostructure and absolute configura-tion of auripyrone B has also been determined.

Total synthesis of auripyrones A and B and …

AB - (Figure Presented) The winner takes it aldol: The total synthesis of auripyrones A and B was achieved using a diastereoselective aldol-type reaction with 2, 6-diethyl-3, 5-dimethyl-4-pyrone as a key step. The stereostructure and absolute configura-tion of auripyrone B has also been determined.

T1 - Total synthesis of auripyrones A and B and determination of the absolute configuration of auripyrone B
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