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Reaction of Dimedone and Benzaldehyde.

In rats depleted of glutathione,either by simultaneous exposure to acrolain (Lam et al., 1985) or by ipinjection with phorone (2,6-dimethyl-2,5-heptadien-4-one) (Casanova &Heck, 1987) a significant increase in the yield of formaldehyde-inducedDNA protein cross-links was observed, suggesting that the formaldehydedehydrogenase-catalyzed oxidation of formaldehyde is an importantdefence mechanism against the covalent binding of formaldehyde withnucleic acids in the nasal respiratory mucosa.

- Mechanisms involved in the carcinogenicity of formaldehyde, such as the effectiveness of mucus as a barrier, the genotoxic consequences of DNA-protein cross-links, and the role of tissue damage, should be studied in more detail.

Reaction mechanism for synthesis of dimedone : …

Reaction of Dimedone and Benzaldehyde: A Discovery …

Reaction of Dimedone and Benzaldehyde: ..

Follow-ing a survival time of 30 min or more, radioactivity appeared in thetissues with a high cell turnover (blood-forming organs, lymphoid sys-tem, gastrointestinal mucosa) and in those with a high rate of proteinsynthesis (exocrine pancreas, salivary glands) (Johansson & Tjalve,1978).

Use of products containing formaldehyde in medicinal and other technical areasa-------------------------------------------------------------------------Area Use ------------------------------------------------------------------------- Detergents and cleaning Preservative in soaps, detergents, cleaning agents industry agents Cosmetics industry Preservative in soaps, deodorants, shampoos, etc; additive in nail hardeners and products for oral hygiene Sugar industry Infection inhibitor in producing juices Medicine Disinfection, sterilization, preservation of preparations Petroleum industry Biocide in oil well-drilling fluids; auxiliary agent in refining Agriculture Preservation of grain, seed dressing, soil disinfection, rot protection of feed, nitrogen fertilizer in soils, protection of dietary protein in ruminants (animal nutrition) Rubber industry Biocide for latex; adhesive additive; anti- oxidizer additive also for synthetic rubber Metal industry Anti-corrosive agent; vehicle in vapour depositing and electroplating processes Leather industry Additive to tanning agents Food industry Preservation of dried foods; disinfection of containers; preservation of fish and certain oils and fats; modifying starch for cold swelling Wood industry Preservative Photographic industry Developing accelerator; hardener for gelatin layers -------------------------------------------------------------------------a Modified from: BASF (1984).

Solution-Mechanism of the synthesis of dimedone

The Kinetics and Mechanism of the Reaction of Formaldehyde with Dimedone.

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Conjugate addition - Dimedone synthesis - ChemTube3D


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