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A Rose Oxide Synthesis: Synthetic Communications: Vol …

We studied the role of nitric oxide (NO) synthesis in amelioration of blood pressure elevation during dietary salt loading in transgenic mice overexpressing sodium proton exchanger. Systolic blood pressure rose after starting salt loading only in the high-salt group of transgenic mice. However, this elevation of blood pressure was not continued. Urinary excretion of inorganic nitrite and nitrate in the high-salt group of transgenic mice was significantly higher than in the high-salt group of control mice. These results suggest that increased NO synthesis in response to salt loading is one of the anti-hypertensive mechanisms in transgenic mice overexpressing sodium proton exchanger.

N2 - We studied the role of nitric oxide (NO) synthesis in amelioration of blood pressure elevation during dietary salt loading in transgenic mice overexpressing sodium proton exchanger. Systolic blood pressure rose after starting salt loading only in the high-salt group of transgenic mice. However, this elevation of blood pressure was not continued. Urinary excretion of inorganic nitrite and nitrate in the high-salt group of transgenic mice was significantly higher than in the high-salt group of control mice. These results suggest that increased NO synthesis in response to salt loading is one of the anti-hypertensive mechanisms in transgenic mice overexpressing sodium proton exchanger.

, Synthesis and odor of optically active rose oxide, Tetrahedron Letters 43 (Oct

Synthesis of Rose Oxide - J-STAGE Home

A Rose Oxide Synthesis - ResearchGate

AB - We studied the role of nitric oxide (NO) synthesis in amelioration of blood pressure elevation during dietary salt loading in transgenic mice overexpressing sodium proton exchanger. Systolic blood pressure rose after starting salt loading only in the high-salt group of transgenic mice. However, this elevation of blood pressure was not continued. Urinary excretion of inorganic nitrite and nitrate in the high-salt group of transgenic mice was significantly higher than in the high-salt group of control mice. These results suggest that increased NO synthesis in response to salt loading is one of the anti-hypertensive mechanisms in transgenic mice overexpressing sodium proton exchanger.

Syntheses of rose oxide (6a) and dihydrorose oxide (6b) from readily avairable stairable starting material are described. The synthetic route route is shown in Scheme-1. The radical addition reaction of 3-ethoxy-3-methylbutanal (2a) to 3-butenyl-3-methyl acetate (1) initiated by benzoyl peroxide gave 7-ethoxy-3, 7-dimethyl-5-oxooctyl acetate (3a) in 42% yield. 7-Ethoxy-5-hydroxy-3, 7-dimethyloctyl acetate (4a) was obtained from (3a) with sodium borohydride in 96% yield. Hydrolysis of (4a) with 10% NaOH gave 7-ethoxy-3, 7-dimethyl-1, 5-octanediol (5a) in 95% yield. Transformation of (5a) into rose oxide (6a) was accomplished by deethoxylative cyclization of (5a) on treatment with 10% H2SO4 at 100°C (60% yield). The product (6a) was a mixture of -and -rose oxide (=90/10).
Similarly, dihydrorose oxide (6b) was prepared from 3, 7-dimethyl-5-oxooctyl acetate (3b) which was obtained from (1) and 3-methylbutanal (2b).

Synthesis of (-)-cis-rose oxide from D-glucose - …

A Rose Oxide Synthes..

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