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He prepared it by reduction of a phenyl diazonium salt ..

Alkanes, Alkenes, Alkynes, Aromatics-arenes, Halogenoalkanes, Alcohols (prim/sec/tert), Phenols, Ethers, Aldehydes, Ketones, Carboxylic acids, Acid/acyl chlorides, Acid Anhydrides, Acid/acyl Amides, Esters, Nitriles, Amines (prim/tert/sec), Quaternary ammonium salts, Nitro-aromatics, Diazonium salts and dyes, Sulphonic (sulfonic) acids and a variety possible Aromatic Compounds and Organic Nitrogen Compounds are also included.

This involves theaddition of an appropriate salt containing the desired nucleophile to the cold,aqueous solution containing the diazonium ion and the allowing the temperatureto ascend to room temperature.

Inparticular, N,N-dimethylaniline reacts readily with aryl diazonium ions as shownbelow:

Aniline is first converted to diazonium salt by treating it ..

In this way, the diazonium ion decomposes to thearyl carbocation, which then reacts with the appropriate nucleophile.

In thecase of aliphatic R groups, the diazonium ions are extremely unstable, rapidlydecomposing to give carbocations which undergo reaction with whatevernucleophiles may be present (such as water).

Even whenthese diazonium ions are formed at ice bath temperatures, they lose nitrogenextremely quickly, forming a carbocation, which then reacts with availablenucleophiles (e.g., solvent or chloride ion).

Diazonium compound : definition of Diazonium compound …

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Definitions of Diazonium compound ..


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